Preheat oven to 350F and line a 12-cup muffin tin with paper wrappers. Set aside.
In a large bowl, whisk oil, sugars, eggs, egg yolk, buttermilk, and vanilla until smooth.
In a medium bowl, combine flour, cocoa, instant espresso, baking powder, baking soda, and salt. Fold flour mixture into liquid until batter is just combined (batter will be thin).
Fill muffin cups 3/4 full of batter (do not overfill past 3/4 otherwise cupcakes may overflow cups during baking). Bake cupcakes at 350F 20-25 minutes until a toothpick inserted in center of cupcake comes out clean. Cool cupcakes completely on a wire cooling rack.